Analysis of Copper and its Alloys by W. T. Elwell

By W. T. Elwell

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In copper, simple and leaded brasses, and bronzes. The following elements, each present in amounts up to at least the concentration stated, do not interfere: 0-1 per cent of bismuth or phosphorus, 0*5 per cent of arsenic or manganese, and 1 per cent of iron or nickel. 1. 1. Special Reagents STANDARD ANTIMONY SOLUTION. Dissolve 0 1 g of antimony in 15 ml of cone, hydrochloric acid and 2 ml of cone, nitric acid ; warm to assist solution of the antimony, then cool. Make all dilutions with cone, hydrochloric acid.

Filter the ether extract through a dry N o . 41 Whatman paper (9 cm) into a dry 1-cm cell, and immediately measure the optical density at a wavelength of 553 ηιμ. 3. Procedure. Transfer 0-1 g of the sample (Note) to a beaker (50 ml), add 5 ml of cone, hydrochloric acid and 1 ml of cone, nitric acid, then continue as described under Preparation of Calibration Graph. Calculate the antimony content of the sample, using the calibration graph. REPRODUCIBILITY: 0-002 AT 0 0 2 PER CENT LEVEL NOTE. This weight of sample is suitable for antimony contents up to about 0-025 per cent.

Where larger amounts of antimony are present, use a 0-1-g sample, dissolve as stated, dilute the solutions to 100 ml with cone, hydrochloric acid, and take an aliquot containing about \5μgoΐ antimony. CHAPTER 6 ARSENIC SEVERAL methods are available for determining arsenic in non[ 3 4] ferrous materials. In B S 1 8 0 0 * two procedures are given; one, suitable for determining arsenic above about 0 - 2 per cent, is based on distillation (and iodimetric titration) of arsenous chloride from a solution containing ferric chloride, calcium chloride and hydrochloric acid.

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